@article{fdi:39872, title = {{O}n the novel free porphyrins corallistin {B}, {C}, {D}, and {E} : isolation from the demosponge {C}orallistes sp. of the {C}oral {S}ea and reactivity of their nickel (2) complexes toward formylating reagents}, author = {{D}'{A}mbrosio, {M}. and {G}uerriero, {A}. and {D}ebitus, {C}{\'e}cile and {R}ibes, {O}livier and {P}ietra, {F}.}, editor = {}, language = {{ENG}}, abstract = {{R}eported here are the novel free corallistin {B}, {C}, {D}, and {E}, isolated as methyl esters 2a, 3a, 4a, and 5a, respectively, from the sponge #{C}orallistes$ sp.(#{L}ithistida$) collected at the basis of the {S}outh {N}ew {C}aledonian coral reef. {A} protocol is also established for formulation of their {N}i{II} complexes, which show a different reactivity pattern toward {DMF}/{POCI}3 from metal complexes of deuteroporphyrin {IX} (isolate as 6a) also present in the sponge, the new corallistins, which may be thought to derive from protoporphyrin via heme, account for an amazing 60% of the et{OH} extract from the sponge. ({R}{\'e}sum{\'e} d'auteur)}, keywords = {{INVERTEBRE} {AQUATIQUE} ; {SUBSTANCE} {NATURELLE} ; {STRUCTURE} {CHIMIQUE} ; {ACTIVITE} {BIOLOGIQUE} ; {EPONGE} ; {CORALLISTINE} ; {NOUVELLE} {CALEDONIE}}, booktitle = {}, journal = {{H}elvetica {C}himica {A}cta}, volume = {76}, numero = {}, pages = {1489--1496}, ISSN = {0018-019{X}}, year = {1993}, DOI = {10.1002/hlca.19930760410}, URL = {https://www.documentation.ird.fr/hor/fdi:39872}, }