@article{fdi:010095910, title = {{W}hen chemistry meets taxonomy : {S}tudying glycolipidic chemomarkers in pelagic {S}argassum spp. ({P}haeophyceae) using molecular networking}, author = {{N}irma, {C}. and {S}tiger-{P}ouvreau, {V}. and {L}evasseur, {M}. and {T}ouboul, {D}. and {C}onnan, {S}. and {P}etek, {S}ylvain}, editor = {}, language = {{ENG}}, abstract = {{T}o chemically differentiate the three pelagic {S}argassum morphotypes co-occurring in floating rafts and drifting across the {A}tlantic {O}cean before stranding on {W}est {A}frican, {C}aribbean, and {A}tlantic {M}exican coastlines, we conducted an investigation of their metabolomic profiles. {H}ydroethanolic extracts from open-sea raft specimens were analyzed using liquid chromatography-tandem mass spectrometry ({LC}-{MS}2), and the resulting spectra were processed through feature-based molecular networking with {M}et{G}em software. {S}everal glycolipids were putatively identified through spectral matching and manual annotation, predominantly associated with {S}. natans var. wingei, {S}. natans var. natans, and {S}. fluitans var. fluitans. {T}hese findings were corroborated by statistical analyses of 1{H} {NMR} spectral fingerprints. {T}his study represents a chemotaxonomic assessment of pelagic {S}argassum utilizing molecular networking, demonstrating its efficient utility for putative chemomarker identification. {W}e further discuss the taxonomic status of the three varieties in light of our chemical data, along with observed physiological distinctions among the morphotypes.}, keywords = {chemomarkers ; glycolipids ; molecular network ; {S}argassum}, booktitle = {}, journal = {{J}ournal of {P}hycology}, volume = {[{E}arly access]}, numero = {}, pages = {[14 p.]}, year = {2025}, DOI = {10.1111/jpy.70116}, URL = {https://www.documentation.ird.fr/hor/fdi:010095910}, }