@article{fdi:010093473, title = {{L}ithium mica clasts document magmatic evolution prior to eruption in the {M}acusani volcanic field in {P}eru}, author = {{T}orrĂ³, {L}. and {R}amirez-{B}riones, {J}. and {S}anandres-{F}lores, {M}. {K}. and {M}onnier, {L}. and {V}illanova-de-{B}enavent, {C}. and {Z}anetti, {K}. {A}. and {K}onrad, {K}. and {V}allance, {J}. and {L}aurent, {O}. and {S}alvi, {S}. and {B}aby, {P}atrice and {P}roenza, {J}. {A}. and {B}achmann, {O}. and {N}ieto, {F}.}, editor = {}, language = {{ENG}}, abstract = {{T}ypically found in rare-metal granites and pegmatites, lithium micas are increasingly considered a resource for lithium as global demand surges. {I}n a recently discovered major lithium resource within the {M}acusani {V}olcanic {F}ield in {P}eru, lithium mica crystal clasts hosted by a tuffaceous mudstone represent an important ore constituent. {T}he mm-scale mica clasts comprise a zinnwaldite core and a lepidolite rim. {C}ompositionally similar to micas in global peraluminous, rare-metal-rich leucogranites and {LCT} pegmatites, they exhibit enrichment in incompatible, fluid-mobile lithophile elements relative to micas in other volcanogenic and intrusive units in the {M}acusani {V}olcanic {F}ield. {T}he compositions of the mica crystal clasts record high degrees of magmatic differentiation and exsolution of a magmatic vapor phase during their crystallization in a ligand-rich, peraluminous crystal mush. 40{A}r/39{A}r dating of zinnwaldite-lepidolite crystal clasts reveals cooling between 8823 +/- 9 and 8717 +/- 44 ka, coinciding with a regional magmatic lull in the {C}entral {A}ndes of southern {P}eru. {A} general slowdown in magmatic activity and a hiatus in volcanism may have contributed to extreme differentiation and pre-eruptive volatile build-up. {T}his study provides crucial insights for lithium exploration, highlighting volcanogenic-sedimentary lithium mica deposits as a promising exploration target in peraluminous volcanic fields.}, keywords = {{C}entral {A}ndes ; {N}eogene ignimbrite {P}rovince of the central {A}ndes ; {V}olcanogenic lithium deposits ; {L}epidolite ; {Z}innwaldite ; {T}ransmission electron microscopy ; {PEROU} ; {ANDES} ; {MACUSANI} {VOLCAN}}, booktitle = {}, journal = {{S}cientific {R}eports - {N}ature}, volume = {15}, numero = {1}, pages = {13023 [16 p.]}, ISSN = {2045-2322}, year = {2025}, DOI = {10.1038/s41598-025-96173-6}, URL = {https://www.documentation.ird.fr/hor/fdi:010093473}, }