Cambou A. auteur aut IRD Allory V. auteur aut IRD Cardinael R. auteur aut IRD Carvalho Vieira L. auteur aut IRD Barthès Bernard auteur aut IRD text journalArticle eng text/pdf reformatted digital access There is increasing demand for data on soil organic carbon (SOC) stock (SSOC; kgC m-2), but the acquisition of such data, which relies on the determination of volumetric SOC content (SOCv; gC dm-3), is often tedious or complex. Visible and near infrared reflectance spectroscopy (VNIRS) has proven useful for soil characterization, but has rarely been used for direct prediction of SOCv. The objectives of this work were: (i) to compare SOCv predictions using VNIR spectra collected in situ vs. on 2-mm sieved air-dried soil (laboratory conditions), on three sample sets separately (with in situ spectra collected differently for each set); and (ii) to assess SOCv prediction in independent validation using laboratory spectra from all sets.Predictions of SOCv were more accurate using laboratory than in situ spectra for two sets, but not for the third set, where coarse particles content was rather high and variable. Considering the total set of laboratory spectra, predictions in independent validation (leave-one-site-out) yielded accurate SOCv and SSOC predictions (standard errors of prediction were 1.9 gC dm-3 and 0.36 kgC m-2 at 0-30 cm depth, respectively). This result was achieved using local partial least squares regression (PLSR), based on spectral neighbors, which noticeably outperformed global PLSR (which uses all calibration samples equally), as often reported when using large soil spectral libraries for independent validation. Finally, this work demonstrated that SSOC could be quantified accurately using a VNIRS library built on archive soil samples, which offers important perspectives for SSOC accounting. specialized FRANCE 068 5 100024 [15 ] 2021 2667-0062 https://www.documentation.ird.fr/hor/fdi:010090926 10.1016/j.soisec.2021.100024 2667-0062 [F B010090926] https://www.documentation.ird.fr/hor/fdi:010090926 https://horizon.documentation.ird.fr/exl-doc/pleins_textes/2024-07/010090926.pdf IRD - Base Horizon / Pleins textes 2024-05-28 2025-02-24 fdi:010090926 fre