@article{fdi:010064218, title = {{O}ccurrence and distribution of glycerol dialkanol diethers and glycerol dialkyl glycerol tetraethers in a peat core from {SW} {T}anzania}, author = {{C}offinet, {S}. and {H}uguet, {A}. and {W}illiamson, {D}avid and {B}ergonzini, {L}. and {A}nquetil, {C}. and {M}ajule, {A}. and {D}erenne, {S}.}, editor = {}, language = {{ENG}}, abstract = {{I}soprenoid and branched glycerol dialkanol diethers (iso {GDD}s and br {GDD}s) have recently been detected in various environments, including sediment, soil and peat deposits. {T}heir structures strongly resemble those of glycerol dialkyl glycerol tetraethers ({GDGT}s). {N}evertheless, the origin of {GDD}s and their link to {GDGT}s remain unclear. {H}ere we examined the concentration and distribution of iso {GDD}s and br {GDD}s, together with those of iso {GDGT}s and br {GDGT}s along a 4 m peat core from {T}anzania. {W}hereas br {GDD}s have only been detected to date in their core lipid ({CL}) form, we report here, for the first time, br {GDD}s in both {CL} and intact polar lipid ({IPL}) forms, suggesting a biosynthetic origin for br {GDD}s. {C}oncentrations of br {GDGT}s and br {GDD}s on one hand and of iso {GDGT}s and iso {GDD}s on the other hand, were observed to significantly co-vary ({R}-2 0.49-0.58; p < 0.05), both for the {CL} and {IPL} fractions. {M}oreover, the fractional abundance of each {GDD} correlated significantly with that of its {GDGT} analogue ({R}-2 0.33-0.97; p < 0.05). {T}aken together, the data show that {GDD}s and {GDGT}s are closely related and likely take part in common metabolic pathways, although the hypothesis of {GDD}s being degradation products of {GDGT}s cannot be excluded.}, keywords = {{GDGT}s ; {GDD}s ; {P}eat core ; {T}anzania ; {TANZANIE}}, booktitle = {}, journal = {{O}rganic {G}eochemistry}, volume = {83-84}, numero = {}, pages = {170--177}, ISSN = {0146-6380}, year = {2015}, DOI = {10.1016/j.orggeochem.2015.03.013}, URL = {https://www.documentation.ird.fr/hor/fdi:010064218}, }