<?xml version="1.0"?>
<oai_dc:dc xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:title>Geochemical and oxygen isotope signatures of mantle corundum megacrysts from the Mbuji-Mayi kimberlite, Democratic Republic of Congo, and the Changle alkali basalt, China</dc:title>
  <dc:creator>/Giuliani, Gaston</dc:creator>
  <dc:creator>Pivin, M.</dc:creator>
  <dc:creator>Fallick, A. E.</dc:creator>
  <dc:creator>Ohnenstetter, D.</dc:creator>
  <dc:creator>Song, Y.</dc:creator>
  <dc:creator>Demaiffe, D.</dc:creator>
  <dc:subject>Oxygen isotopes</dc:subject>
  <dc:subject>Chemistry</dc:subject>
  <dc:subject>Corundum</dc:subject>
  <dc:subject>Kimberlite</dc:subject>
  <dc:subject>Alkali basalt</dc:subject>
  <dc:subject>Origin</dc:subject>
  <dc:subject>Mantle</dc:subject>
  <dc:description>Oxygen isotope signatures of ruby and sapphire megacrysts, combined with trace-element analysis, from the Mbuji-Mayi kimberlite, Democratic Republic of Congo, and the Changle alkali basalt, China, provide clues to specify their origin in the deep Earth. At Mbuji-Mayi, pink sapphires have 8180 values in the range 4.3 to 5.4 parts per thousand (N=10) with a mean of 4.9 +/- 0.4 parts per thousand, and rubies from 5.5 to 5.6 parts per thousand (N=3). The Ga/Mg ratio of pink sapphires is between 1.9 and 3.9, and in rubies, between 0.6 and 2.6. The blue or yellow sapphires from Changle have delta O-18 values from 4.6 to 5.2 parts per thousand, with a mean of 4.9 +/- 0.2 parts per thousand (N=9). The Ga/Mg ratio is between 5.7 and 11.3. The homogenous isotopic composition of ruby suggests a derivation from upper mantle xenoliths (garnet lherzolite, pyroxenite) or metagabbros and/or lower crustal garnet clinopyroxenite eclogite-type xenoliths included in kimberlites. Data from the pink sapphires from Mbuji-Mayi suggest a mantle origin, but different probable protoliths: either subducted oceanic protolith transformed into eclogite with delta O-18 values buffered to the mantle value, or clinopyroxenite protoliths in peridotite. The Changle sapphires have a mantle O-isotope signature. They probably formed in syenitic magmas produced by low degree partial melting of a spinel Iherzolite source. The kimberlite and the alkali basalt acted as gem conveyors from the upper mantle up to the surface.</dc:description>
  <dc:date>2015</dc:date>
  <dc:type>text</dc:type>
  <dc:identifier>https://www.documentation.ird.fr/hor/fdi:010064156</dc:identifier>
  <dc:identifier>fdi:010064156</dc:identifier>
  <dc:identifier>Giuliani Gaston, Pivin M., Fallick A. E., Ohnenstetter D., Song Y., Demaiffe D.. Geochemical and oxygen isotope signatures of mantle corundum megacrysts from the Mbuji-Mayi kimberlite, Democratic Republic of Congo, and the Changle alkali basalt, China. 2015, 347 (1),  24-34</dc:identifier>
  <dc:language>EN</dc:language>
  <dc:coverage>REPUBLIQUE DEMOCRATIQUE DU CONGO</dc:coverage>
  <dc:coverage>CHINE</dc:coverage>
</oai_dc:dc>
