Raous S. auteur aut IRD Becquer Thierry auteur aut IRD Garnier J. auteur aut IRD Martins E. D. auteur aut IRD Echevarria G. auteur aut IRD Sterckeman T. auteur aut IRD text journalArticle eng text/pdf born digital access An understanding of the biogeochemical behaviour of metals in mine spoil materials is a prerequisite to rehabilitate Ni mining sites. The objective of this study was to characterize the fate of metals in different Ni ore spoil materials as influenced by hydrological conditions and fertilisation practices. In tropical ultramafic complexes, the different stages of lateritic weathering lead to two types of ores, and therefore, to two spoil types. They are mainly either a clay-rich saprolite, so-called "garnierite", enriched in phyllosilicates, or a limonitic material, enriched in Fe oxides. Lysimeter columns were designed to monitor leaching waters through both spoil materials. The garnieritic spoil released higher concentrations of Mg (mean = 2.25 mg L-1), Ni (0.39 mg L-1) and Cr (1.19 mg L-1) than the limonitic spoil (Mg = 0.5 mg L-1: Ni = 0.03 mg L-1 and Cr = 0.25 mg L-1). Chromium was mainly in an anionic form in leaching solutions. As exchangeable pools of Cr(VI) in limonite (980 mg kg(-1) of KH2PO4-extractable Cr) are considerable its release in water may still occur in the case of a pH increase. In mixed spoil, metal concentrations were almost as low as in the limonitic one. The effect of mineral-N fertilisation was a strong release of cations (Ni, Mg) into the leachate. Phosphate amendment did not affect the soil solution composition under experimental conditions. specialized 064 25 11 1746-1755 2010 0883-2927 https://www.documentation.ird.fr/hor/fdi:010052958 10.1016/j.apgeochem.2010.09.001 0883-2927 [F B010052958] https://www.documentation.ird.fr/hor/fdi:010052958 https://www.documentation.ird.fr/intranet/publi/2010/12/010052958.pdf Accès réservé (Intranet de l'IRD) IRD - Base Horizon / Pleins textes 2011-01-10 2017-08-23 fdi:010052958 fre