%0 Journal Article %9 ACL : Articles dans des revues avec comité de lecture répertoriées par l'AERES %A Basile Doelsch, Isabelle %A Amundson, R. %A Stone, W. E. E. %A Borschneck, D. %A Bottero, J. Y. %A Moustier, S. %A Masin, F. %A Colin, Fabrice %T Mineral control of carbon pools in a volcanic soil horizon %D 2007 %L fdi:010037811 %G ENG %J Geoderma %@ 0016-7061 %K density fractions ; soil organic matter ; mineralogy ; organomineral complexes ; carbon sequestration %M ISI:000243842700023 %N 3-4 %P 477-489 %R 10.1016/j.geoderma.2006.10.006 %U https://www.documentation.ird.fr/hor/fdi:010037811 %> https://www.documentation.ird.fr/intranet/publi/2007/03/010037811.pdf %V 137 %W Horizon (IRD) %X The aim of this study was to characterize carbon sequestration by mineralogical control at the scale of a volcanic soil horizon. We adapted the classical density fractionation procedure and focused on the heavy fractions (> 1.9), which we divided into eight organomineral fractions. We characterized them simultaneously through non-destructive mineralogical analyses (XRD and NMR of Al and Si) and organic carbon analyses. The results showed that the largest proportion (82.6%) of organic matter in the horizon was associated with minerals in organomineral complexes. Imogolite type materials bound 6-fold more OM than anorthoclase, and 3.5-fold more OM than iron oxides. In addition, we observed a degree of polymerization of imogolite type materials that was midway between that of allophane and Al in Al-humus complexes. In conclusion, the results of this density fractionation combined with a mineralogical approach suggested that OM in the heavy fractions could be divided into several pools depending on the nature of the minerals. %$ 068