Bolivianine, a new sesterpene with an unusual skeleton from #Hedyosmum angustifolium$, and its isomer, isobolivianine

Bolivianine, a new sesterpene with an unusual skeleton from #Hedyosmum angustifolium$, and its isomer, isobolivianine Acebey Lucia auteur aut IRD Sauvain Michel auteur aut IRD Beck S. auteur aut IRD Moulis C. auteur aut IRD Gimenez A. auteur aut IRD Jullian Valérie auteur aut IRD text journalArticle eng Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made. specialized 076 Organic Letters 9 23 4693-4696 2007 1523-7060 https://www.documentation.ird.fr/hor/PAR00002028 10.1021/ol7015725 1523-7060 https://www.documentation.ird.fr/hor/PAR00002028 IRD - Base Horizon / Pleins textes 2007-12-21 2017-08-23 PAR00002028 fre