@article{PAR00002028, title = {{B}olivianine, a new sesterpene with an unusual skeleton from {H}edyosmum angustifolium, and its isomer, isobolivianine}, author = {{A}cebey, {L}ucia and {S}auvain, {M}ichel and {B}eck, {S}. and {M}oulis, {C}. and {G}imenez, {A}. and {J}ullian, {V}al{\'e}rie}, editor = {}, language = {{ENG}}, abstract = {{B}olivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of {H}edyosmum angustifolium ({C}hloranthaceae), with isobolivianine, an isomer formed under acidic conditions. {T}he structure and relative stereochemistry were elucidated on the basis of spectroscopic data. {A} hypothesis for biogenesis was made.}, keywords = {}, booktitle = {}, journal = {{O}rganic {L}etters}, volume = {9}, numero = {23}, pages = {4693--4696}, ISSN = {1523-7060}, year = {2007}, DOI = {10.1021/ol7015725}, URL = {https://www.documentation.ird.fr/hor/{PAR}00002028}, }