%0 Journal Article
%9 ACL : Articles dans des revues avec comité de lecture répertoriées par l'AERES
%A Cossa, D.
%A Fanget, A. S.
%A Chiffoleau, J. F.
%A Bassetti, M. A.
%A Buscail, R.
%A Dennielou, B.
%A Briggs, K.
%A Arnaud, M.
%A Guédron, Stéphane
%A Berne, S.
%T Chronology and sources of trace elements accumulation in the Rhone pro-delta sediments (Northwestern Mediterranean) during the last 400 years
%B Special issue of MERMEX project : recent advances in the oceanography of the Mediterranean Sea
%D 2018
%E Sempéré, R.
%E Durrieu de Madron, X.
%E Guieu, C.
%E Pairaud, I.
%L fdi:010073066
%G ENG
%J Progress in Oceanography
%@ 0079-6611
%K MEDITERRANEE ; FRANCE
%K RHONE DELTA
%M ISI:000434004400014
%N Special issue
%P 161-171
%R 10.1016/j.pocean.2017.01.008
%U https://www.documentation.ird.fr/hor/fdi:010073066
%> https://www.documentation.ird.fr/intranet/publi/2018/06/010073066.pdf
%V 163
%W Horizon (IRD)
%X The Rhone pro-delta sediments receive the particulate inputs from the Rhone River, the largest freshwater discharge of the Western Mediterranean Sea. Trace element (TEs: Ag, Cd, Co, Cr, Cu, Ni, Pb, and Zn) concentrations and stable Pb isotope ratios were determined along a 7.7-m-long sediment core collected from the Rhone prodeltaic lobe, archiving the deposits of the last 400 years. Trace element mean concentrations during the pre-industrialized era (before 1850 CE) were no different from the average composition of Earth's upper crust, except for Cr. Principal component analysis, performed on TEs and tracers, suggests three origins for TEs that we identified as (i) marine biogenic material (Ag, Cd), (ii) ultramafic rocks (Li, Cr, Ni), and (iii) other clay minerals (Co, Cu, Pb and Zn). During the pre-industrial period, several changes in the TE/AI ratios coincided with flood events or/and modifications in the channelization of the Rhone River mouth. Some frequencies in the TEs temporal variations allow us to hypothesize some influence of climate variation. Sediments deposited after 1850 CE exhibited concentrations of certain TEs exceeding 1.3-3.5 times the concentrations of the pre-industrial era (Ag > Cd-Pb > Cu-Zn). Principal component analysis, performed on post-1850 CE data, allows to distinguish pristine and "anthropogenically impacted" TEs. Pristine TEs, such as Co, Cr, and Ni, are linked with clay markers (Al, Li and Fe), Co and Ni are associated with Mn-enrichment, whereas Cr is correlated with Fe. "Anthropogenically impacted" elements consist of Ag, Cd, Cu, Pb, and Zn. Vertical profiles show that TE contamination has increased dramatically after the IInd World War and reached a maximum between 1970 and 1980, consistently with anthropogenic atmospheric emissions changes. Sediment deposited on the Rhone prodelta at the beginning of XVIIth Century have Pb-206/207 ratios close to values of natural Pb (1.200), whereas sediments deposited after 1850 CE are clearly contaminated by European gasoline and industrial Pb pools (<1.180). In addition, peak-events can be related to flooding periods, natural and man-induced channelization of the Rhone River mouth, or diagenetic processes.
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