@article{fdi:010071446, title = {{S}creening triclocarban and its transformation products in river sediment using liquid chromatography and high resolution mass spectrometry}, author = {{S}ouchier, {M}. and {B}enali-{R}aclot, {D}. and {B}enanou, {D}. and {B}oireau, {V}. and {G}omez, {E}. and {C}asellas, {C}. and {C}hiron, {S}erge}, editor = {}, language = {{ENG}}, abstract = {{A}n analytical method was developed and validated for the target screening of triclosan ({TCS}), triclocarban ({TCC}) and its lesser and higher chlorinated congeners namely, 4,4'-dichlorocarbanilide ({DCC}) 3,3',4,4'-tetrachlorocarbanilide (3-{C}l-{TCC}) and 2,3',4,4'-tetrachlorocarbanilide (2-{C}l-{TCC}) in river sediment. {S}ediment samples were extracted by pressurized liquid extraction and quantification and identification of target compounds were carried by liquid chromatography high resolution mass spectrometry ({LC}-{HRMS}). {T}he overall method recoveries were 89% with relative standard deviations below 6%. {M}ethod detection limits ranged from 0.01 to 0.12 ng/g. {T}he usefulness of the method was demonstrated on sediment samples collected downstream of three wastewater treatment plants in an attempt to provide with a set of occurrence data of these biocides in {F}rance and for a better understanding of their fate in river. {M}ajor results are the following: {TCC}, {DCC} and 3-{C}l-{TCC} were ubiquitously detected demonstrating that these emerging contaminants have been probably overlooked in {F}rance. {R}eductive dechlorination of {TCC} into {DCC} was also ubiquitous but predominated in anoxic sediment. 3-{C}l-{TCC} is probably more persistent than {TCC} and {LC}-{HRMS} enabled the detection and identification of a suite of other chlorinated biocides in river sediment.}, keywords = {{T}riclocarban ; {S}ediment ; {R}eductive dechlorination ; {T}etrachlorocarbanilides ; {H}igh resolution mass spectrometry ; {FRANCE}}, booktitle = {}, journal = {{S}cience of the {T}otal {E}nvironment}, volume = {502}, numero = {}, pages = {199--205}, ISSN = {0048-9697}, year = {2015}, DOI = {10.1016/j.scitotenv.2014.08.108}, URL = {https://www.documentation.ird.fr/hor/fdi:010071446}, }