@article{fdi:010071353, title = {{S}porothriolide-related compounds from the fungus {H}ypoxylon monticulosum {CLL}-205 isolated from a {S}phaerocladina sponge from the {T}ahiti {C}oast}, author = {{L}eman-{L}oubi{\`e}re, {C}. and {L}e {G}off, {G}. and {R}etailleau, {P}. and {D}ebitus, {C}{\'e}cile and {O}uazzani, {J}.}, editor = {}, language = {{ENG}}, abstract = {{T}wo sporothriolide-related compounds were obtained from an extract of the fungus {H}ypoxylon monticulosum {CLL}-205, isolated from a {S}phaerocladina sponge collected from the {T}ahiti coast. {C}ompound 2 is a deoxy analogue of sporothric acid (4). {C}ompound 3 is a newly reported unusual scaffold combining sporothriolide (1) and trienylfuranol {A} (5) moieties, through a {D}iels-{A}lderase-type reaction. {V}arious experimental and analytical arguments supported the biocatalytic origin of compound 3. {T}he structures of the isolated compounds were elucidated using 1{D} and 2{D} {NMR}, {HRMS}, and {IR} data. {T}he structure and the absolute configuration of 3 were unambiguously confirmed by a single-crystal {X}-ray diffraction analysis.}, keywords = {{TAHITI} ; {PACIFIQUE}}, booktitle = {}, journal = {{J}ournal of {N}atural {P}roducts}, volume = {80}, numero = {10}, pages = {2850--2854}, ISSN = {0163-3864}, year = {2017}, DOI = {10.1021/acs.jnatprod.7b00714}, URL = {https://www.documentation.ird.fr/hor/fdi:010071353}, }