@article{fdi:010068163, title = {{C}admium in the waters off {S}outh {M}orocco : nature of particles hosting {C}d and insights into the mechanisms fractionating {C}d from phosphate}, author = {{W}aeles, {M}. and {P}lanquette, {H}. and {A}fandi, {I}. and {D}elebecque, {N}. and {B}outhir, {F}. and {D}onval, {A}. and {S}helley, {R}. {U}. and {A}uger, {P}ierre-{A}ma{\¨e}l and {R}iso, {R}. {D}. and {T}ito de {M}orais, {L}uis}, editor = {}, language = {{ENG}}, abstract = {{I}n this study, we report the distributions of total dissolvable cadmium and particulate cadmium from 27 stations in southern {M}oroccan coastal waters (22 degrees {N}-30 degrees {N}), which is part of the {N}orth-{W}est {A}frican upwelling system. {T}hese distributions were predominantly controlled by upwelling of the {N}orth {A}tlantic {C}entral {W}aters ({NACW}s) and uptake by primary production. {A}tmospheric inputs and phosphogypsum slurry inputs from the phosphate industry at {J}orf {L}asfar (33 degrees {N}), recently estimated as an important source of dissolved cadmium (240 t {C}d yr(-1)), are at best of minor importance for the studied waters. {O}ur study provides new insights into the mechanisms fractionating cadmium from phosphate. {I}n the upper 30 m, the anomalies observed in terms of {C}d:{P} ratios in both the particulate and total dissolvable fractions were related to an overall preferential uptake of phosphate. {W}e show that the type of phytoplanktonic assemblage (diatoms versus dinoflagellates) is also a determinant of the fractionation intensity. {I}n subsurface waters (30-60 m), a clear preferential release of {P} (versus {C}d) was observed indicating that remineralization in {O}xygen {M}inimum {Z}ones is a key process in sequestering {C}d.}, keywords = {{MAROC} ; {ATLANTIQUE}}, booktitle = {}, journal = {{J}ournal of {G}eophysical {R}esearch : {O}ceans}, volume = {121}, numero = {5}, pages = {3106--3120}, ISSN = {2169-9275}, year = {2016}, DOI = {10.1002/2016jc011688}, URL = {https://www.documentation.ird.fr/hor/fdi:010068163}, }