%0 Journal Article
%9 ACL : Articles dans des revues avec comité de lecture répertoriées par l'AERES
%A Silipo, A.
%A Di Lorenzo, F.
%A De Felice, A.
%A Vanacore, A.
%A De Castro, C.
%A Gully, Djamel
%A Lanzetta, R.
%A Parrilli, M.
%A Giraud, Eric
%A Molinaro, A.
%T Structural and conformational study of the O-polysaccharide produced by the metabolically versatile photosynthetic bacterium Rhodopseudomonas palustris strain BisA53
%D 2014
%L fdi:010062636
%G ENG
%J Carbohydrate Polymers
%@ 0144-8617
%K Rhodopseudomonas palustris ; Lipopolysaccharide ; C-branched sugar ; NMR ; spectroscopy ; Molecular modeling
%M ISI:000343613800049
%P 384-391
%R 10.1016/j.carbpol.2014.08.037
%U https://www.documentation.ird.fr/hor/fdi:010062636
%> https://www.documentation.ird.fr/intranet/publi/2014/11/010062636.pdf
%V 114
%W Horizon (IRD)
%X Rhodopseudomonas palustris is a purple photosynthetic bacterium characterized by a versatile nature and a remarkable ability to adapt to various environments. In this work, we focused our attention to its membrane characteristics and defined the structural and conformational features of the O-chain polysaccharide of LPS isolated from R. palustris strain BisA53. This strain produces a polymer with a trisaccharide repeating unit characterized by D-rhamnose, 3-deoxy-D-lyxo-2-heptulosaric acid (Dha), and a novel C-branched monosaccharide, a 4-amino-4,6-dideoxy-3-C-methyl-2-O-methyl-alpha-L-glucopyranose whose absolute configuration has been determined by a combination of 2D NMR spectroscopy and molecular mechanic and dynamic simulation.
%$ 084 ; 020