Berquo T. S., Imbernon R. A. L., Blot Alain, Franco D. R., Toledo M. C. M., Partiti C. S. M. (2007). Low temperature magnetism and Mossbauer spectroscopy study from natural goethite. Physics and Chemistry of Minerals, 34 (5), p. 287-294. ISSN 0342-1791.
Titre du document
Low temperature magnetism and Mossbauer spectroscopy study from natural goethite
Berquo T. S., Imbernon R. A. L., Blot Alain, Franco D. R., Toledo M. C. M., Partiti C. S. M.
Source
Physics and Chemistry of Minerals, 2007,
34 (5), p. 287-294 ISSN 0342-1791
In this work a magnetic characterization was made of natural goethite from Burkina Faso, Africa, by using low temperature magnetization curves, hysteresis loops, Mossbauer spectroscopy at room temperature and 4.2 K, and AC susceptibility from 10 to 400 K. The samples are from two distinct geological sites that underwent different weathering processes. All measurements point to the occurrence of typical high coercivity goethite. Through Mossbauer spectroscopy sample BL44, from Gangaol, northeast Burkina Faso showed relaxation effects due to a wide distribution of grain size, including superparamagnetism threshold. AC susceptibility also supports this interpretation. The sample BL50 from Bonga in Burkina Faso is associated with lateritic Ni and in addition to goethite this sample also contained magnetite, as determined by Verwey transition in low temperature measurements as well as a small content of hematite identified by Mossbauer spectroscopy.
