@article{PAR00011057,
  title = {{S}trong gradient of benthic biogeochemical processes along a macrotidal temperate estuary : focus on {P} and {S}i cycles},
  author = {{R}aimonet, {M}. and {A}ndrieux-{L}oyer, {F}. and {R}agueneau, {O}livier and {M}ichaud, {E}. and {K}erouel, {R}. and {P}hilippon, {X}. and {N}onent, {M}. and {M}emery, {L}.},
  editor = {},
  language = {{ENG}},
  abstract = {{T}his study aims to investigate the role of spatial and temporal physical, biological and biogeochemical gradients on sediment biogeochemistry along a macrotidal and {S}i-rich estuary. {S}canning and biogeochemical analyses were performed in the inner, mid and outer {A}ulne {E}stuary ({F}rance) at four seasons. {T}he inner estuary shows high diagenetic activity linked to fluid mud dynamics and river loads. {T}he highest authigenic phosphorus ({A}ut-{P}) concentrations ever found in the literature are observed in the inner estuary (18 mu mol g(-1) {PS} sediment). {T}his is explained by a combination of favorable factors, i.e. the high organic matter and nutrient loads, the reductive conditions, the freshwater properties (low p{H}, {OH}-, sulfate and {M}g2+ concentrations), the increase of particle residence time by the upward convergence of particles due to residual currents, and allochthonous riverine {A}ut-{P}. {W}e suggest that the high {S}i({OH})(4) concentrations (> 400 mu {M}) may even increase {A}ut-{P} precipitation through the increase of {F}e-{P} formation in these low salinity conditions. {I}n the mid estuary, erosion-deposition dynamics dominate in point bars and lead to the succession of poor and rich organic and authigenic phosphorus layers, recording thus the seasonality of matter loads and its seasonal translocation from the inner estuary. {I}n the outer estuary, deposition rates are high and constant and biogeochemical properties are characteristic of marine environments. {T}he precipitation of {A}ut-{P} from free phosphate ({PO}4 (3-)) is lower than in the inner estuary and might be limited by higher {M}g2+ concentrations in saline waters. {T}his study highlights that small macrotidal estuaries, and especially their freshwater sediments, may constitute an important phosphorus sink through the precipitation of {A}ut-{P}. {T}his precipitation could even be enhanced in fresh or brackish environments, thus increasing long term phosphorus storage and altering benthic fluxes of {PO}4 (3-) to the pelagic ecosystem.},
  keywords = {{E}arly diagenesis ; {S}ilicate ; {P}hosphate ; {A}uthigenic phosphorus ; {M}acrotidal ; {E}stuary ; {FRANCE}},
  booktitle = {},
  journal = {{B}iogeochemistry},
  volume = {115},
  numero = {1-3},
  pages = {399--417},
  ISSN = {0168-2563},
  year = {2013},
  DOI = {10.1007/s10533-013-9843-3},
  URL = {https://www.documentation.ird.fr/hor/{PAR}00011057},
}