Acebey Lucia, Sauvain Michel, Beck S., Moulis C., Gimenez A., Jullian Valérie. (2007). Bolivianine, a new sesterpene with an unusual skeleton from Hedyosmum angustifolium, and its isomer, isobolivianine. Organic Letters, 9 (23), p. 4693-4696. ISSN 1523-7060.
Titre du document
Bolivianine, a new sesterpene with an unusual skeleton from Hedyosmum angustifolium, and its isomer, isobolivianine
Organic Letters, 2007,
9 (23), p. 4693-4696 ISSN 1523-7060
Bolivianine, a novel sesterpene with an unprecedented skeleton, has been isolated from the trunk bark of Hedyosmum angustifolium (Chloranthaceae), with isobolivianine, an isomer formed under acidic conditions. The structure and relative stereochemistry were elucidated on the basis of spectroscopic data. A hypothesis for biogenesis was made.
